Prospects of graphene quantum dots preparation using lignocellulosic wastes for application in photofermentative hydrogen production

Graphene quantum dots (GQDs) are a novel carbon nanomaterial from the graphene family due to their unique physicochemical properties and diverse range of applications. However, in terms of the sustainable utility of GQDs, their synthesis methods are the main roadblock because of their high production costs and the release of toxic byproducts during the production processes. Thus, the search for sustainable and economical fabrication methods for preparing GQDs is one of the most essential areas of research for their practical applications. In this context, lignocellulosic biomass (LCB) wastes are a prime choice for the fabrication of GQDs due to their high carbon and cellulose content, which are favorable for being employed as precursors and reducing agents Additionally, LCBs are a prime source of potential bioenergy production, which is currently a key research hotspot to combat environmental pollution, global warming, and energy crises. Therefore, the present review provides feasibility for sustainable and environmentally friendly fabrication of GQDs using LCB wastes for their possible utility in cellulosic biofuel production technology improvement. Furthermore, the prospective of using these GQDs as catalysts in bioenergy production for the development of low-cost biomass-based biofuel production technology has been discussed along with the existing limitations and their sustainable recommendation.